Trifluoroiodomethane → HCID 86743769、化合物

HRID 1199911ノート

反応式

I[As:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[F:15][C:16]([F:19])([F:18])I>>[C:3]1([As:2]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:16]([F:19])([F:18])[F:15])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

反応物 2

HCID 16843Trifluoroiodomethane

HCID 238215Diphenylarsinous iodide

生成物 1

HCID 86743769HCID 86743769、化合物

実験手順

R. Cullen in an article "Perfluoroalkyl Arsenicals, Part II The Preparation and Properties of Aryl Perfluoroalkyl Arsenicals", reported in Canadian Journal of Chemistry, Volume 38, 1960, pg. 445-451, describes the reaction of iododiphenylarsine with trifluoroiodomethane to produce diphenyltrifluoromethylarsine. Thermal decomposition of diphenyltrifluoromethylarsine resulted in undisclosed black solid deposit.

出典と根拠

ORDレコード: ord-9ae2544f897e4fbcaf08475ad6cf7f8f
出典データセット: uspto-grants-1990_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04904616

反応ノート

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