Hydrochloric Acid → Bistrifluoromethylarsine
反応式
Cl.I[As:3]([C:8]([F:11])([F:10])[F:9])[C:4]([F:7])([F:6])[F:5]>[Zn].O>[F:5][C:4]([AsH:3][C:8]([F:11])([F:10])[F:9])([F:7])[F:6]参加物
5
実験手順
The trifluoromethyl arsine hydrides can be made via direct reaction of the tris-trifluoromethyl arsenic iodides with zinc and hydrochloric acid. For instance, 10 g of zinc, 10 ml of water, and 15 ml of 5N HCl are shaken with 3.80 g of iodo bis-trifluoromethylarsine to give 1.03 g of bistrifluoromethylarsine (b.p. 19° C.), a 43% yield. Trifluoromethylarsine can be made by a similar method (b.p. -12.5° C.).
出典と根拠
- ORDレコード
- ord-ae1182a47e97489a8be4469a14a3dc06
- 出典データセット
- uspto-grants-1990_02
- 特許番号
- US04904616
反応ノート
読み込み中…