Methyl 6-Bromohexanoate → 6-[[3-[(3,4-Dimethylphenyl)amino]-4,6-dinitrophenyl]oxy]hexanoic acid methyl ester

反応式

[CH3:1][C:2]1[CH:3]=[C:4]([NH:9][C:10]2[CH:11]=[C:12]([OH:22])[C:13]([N+:19]([O-:21])=[O:20])=[CH:14][C:15]=2[N+:16]([O-:18])=[O:17])[CH:5]=[CH:6][C:7]=1[CH3:8].[CH3:23][O:24][C:25](=[O:32])[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30]Br>>[CH3:23][O:24][C:25](=[O:32])[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][O:22][C:12]1[C:13]([N+:19]([O-:21])=[O:20])=[CH:14][C:15]([N+:16]([O-:18])=[O:17])=[C:10]([NH:9][C:4]2[CH:5]=[CH:6][C:7]([CH3:8])=[C:2]([CH3:1])[CH:3]=2)[CH:11]=1

参加物

反応物 2

HCID 4170292Methyl 6-Bromohexanoate

HCID 219380413-[(3,4-Dimethylphenyl)amino)-4,6-dinitrophenol

生成物 1

HCID 866047786-[[3-[(3,4-Dimethylphenyl)amino]-4,6-dinitrophenyl]oxy]hexanoic acid methyl ester

実験手順

5 g of 3-[(3,4-dimethylphenyl)amino]-4,6-dinitrophenol was O-alkylated with 6-bromohexanoic acid methyl ester at 70° C. analogously to general operating instructions 8.

出典と根拠

ORDレコード: ord-0c3be54d84034778817dbe478e51744a
出典データセット: uspto-grants-2006_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07115645B2

反応ノート

読み込み中…