Water → HCID 10955768、化合物

HRID 1243958ノート

反応式

HRID 1243958 の反応式
[C:1]([C:3]1[CH:17]=[CH:16][C:6]([O:7][C:8]2[CH:13]=[CH:12][C:11]([O:14][CH3:15])=[CH:10][CH:9]=2)=[CH:5][CH:4]=1)#[N:2].[OH2:18]>CS(O)(=O)=O>[CH3:15][O:14][C:11]1[CH:12]=[CH:13][C:8]([O:7][C:6]2[CH:16]=[CH:17][C:3]([C:1]([NH2:2])=[O:18])=[CH:4][CH:5]=2)=[CH:9][CH:10]=1

参加物

4

反応物 2

HCID 962WaterHCID 14902794-(4-methoxyphenoxy)benzonitrile

生成物 1

HCID 10955768HCID 10955768、化合物

試薬・触媒・溶媒 1

HCID 6395Methanesulfonic Acid溶媒

実験手順

4-(4-Cyanophenoxy)-methoxybenzene (7.66 g, 34 mmol) and water (6.13 g, 340 mmol) in methanesulfonic acid (32.7 g) were heated to 80° C. for 16 hours. The cooled mixture was poured onto ice/water and after stirring for 1 hour the solid was collected and air dried yielding 8.4 g of 4-(4-methoxyphenoxy)benzamideas a white solid. GC-MS (m/z, EI): 243 [M]+.

後処理

  1. additionThe cooled mixture was poured onto ice/water
  2. customwas collected
  3. customair dried
  4. customyielding 8.4 g of 4-(4-methoxyphenoxy)benzamideas a white solid

出典と根拠

ORDレコード
ord-fc5824291b5a4724bec697ce5ec4c850
出典データセット
uspto-grants-2006_10
特許番号
US07119201B2

反応ノート

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