Acetone → N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-pyridinesulfonamide

反応式

[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12](=S)[NH:13][S:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)(=[O:16])=[O:15])[N:4]=1.CC(C)=[O:26]>>[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12]([NH:13][S:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)(=[O:16])=[O:15])=[O:26])[N:4]=1

参加物

反応物 2

HCID 180Acetone

HCID 20278358HCID 20278358、化合物

生成物 1

HCID 20278363N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-pyridinesulfonamide

実験手順

A mixture containing 2.7 g of N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminothioxomethyl]-2-pyridinesulfonamide, 2.98 g of mercuric oxide and 75 ml of acetone is stirred at ambient temperature for 60 hours and then filtered. Evaporation of the filtrate in vacuo yields the desired product.

後処理

filtrationfiltered
customEvaporation of the filtrate in vacuo

出典と根拠

ORDレコード: ord-b4ed3855addf497494da9a3705cc2100
出典データセット: uspto-grants-1985_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04522645

反応ノート

読み込み中…

参加物