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Carbon Disulfide → HCID 13561953、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Carbon Disulfide | HCID 6348 | — |
| 反応物 | Furfuryl Alcohol | HCID 7361 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | 2-(Chloromethyl)furan | HCID 219520 | — |
| 反応物 | D-1,2,3,4-Tetrahydronorharman-3-carboxylic acid | HCID 675102 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | HCID 13561953 | HCID 13561953 | — |
反応手順
In the same manner as descsribed in Example 32, (3R)-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid (8.65 g), KOH (4.67 g), carbon disulfide (2.43 ml), 75% ethanol (120 ml) and furfuryl chloride which is prepared from furfuryl alcohol (9.24 g), thionyl chloride (12.34 g) and pyridine (8.94 g) are reacted and treated to give the title compound (2.31 g) as pale yellow powder.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04628057 |
| 出典データセット | uspto-grants-1986_12 |
| ORD ID | ord-4d04b1f0650b4fee9de48418bb2f4bae |
| 出典メモ | uspto-grants-1986_12 |