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Isotridecan-1-ol → 1,2,3,4,5-Pentaisotridecyloxycarbonylcyclopentadiene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isotridecan-1-ol | HCID 33865 | — |
| 反応物 | Pentamethyl cyclopentadiene-1,2,3,4,5-pentacarboxylate | HCID 494485 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 1,2,3,4,5-Pentaisotridecyloxycarbonylcyclopentadiene | HCID 20155084 | 100.2% |
反応手順
7.13 g (20 mmol) of 1,2,3,4,5-pentamethoxycarbonylcyclopentadiene are treated with 20.0 g (100 mmol) of isotridecyl alcohol. 3.12 g (97.5% of the theoretical yield) of methanol are distilled off at 100° C. within 8 h, firstly at 1013 mbar, then at from 363 to 18 mbar. 24 g of 1,2,3,4,5-pentaisotridecyloxycarbonylcyclopentadiene are obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04631243 |
| 出典データセット | uspto-grants-1986_12 |
| ORD ID | ord-06999c9c110c4195ad4f0e20ffd54137 |
| 出典メモ | uspto-grants-1986_12 |