反応式
[F-].[Cs+].[C:3]1([CH3:9])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:10](#N)[CH3:11]>CC([O-])=O.CC([O-])=O.[Pd+2].C1C=CC(P(C2C=CC=CC=2)[C-]2C=CC=C2)=CC=1.C1C=CC(P(C2C=CC=CC=2)[C-]2C=CC=C2)=CC=1.[Fe+2]>[CH:7]1[C:8]2[C:10]3[C:11](=[CH:11][CH:10]=[CH:8][CH:7]=3)[C:9]3[C:9](=[CH:6][CH:5]=[CH:4][CH:3]=3)[C:3]=2[CH:4]=[CH:5][CH:6]=1参加物
5
実験手順
1-trifluoromethanesulfonato-2-trimethylsilylbenzene (3 equivalents) is reacted with 1 equivalent of the appropriate iodoaromatic (see scheme 5a), in the presence of 5 mol % of Pd(OAc)2, 5 mol % of dppf and 4 equivalents of CsF in toluene/acetonitrile, to obtain the desired ligands of the formulae IId), IIe) and IIf).
出典と根拠
- ORDレコード
- ord-dc6baef536d2463899c681964776dcd1
- 出典データセット
- uspto-grants-2013_06
- 特許番号
- US08455112B2
関連ノート
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