化工社化工社 化学情報印刷レポート · 研究参考用
Acetic acid, azido-, ethyl ester → Ethyl (2Z,4E)-2-azido-5-(4-methylphenyl)penta-2,4-dienoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic acid, azido-, ethyl ester | HCID 69480 | — |
| 反応物 | Sodium ethoxide | HCID 2723922 | — |
| 反応物 | p-Methylcinnamaldehyde | HCID 5371802 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Ethyl (2Z,4E)-2-azido-5-(4-methylphenyl)penta-2,4-dienoate | HCID 12378027 | — |
反応手順
Following General Procedure I, a 1.38 M solution of NaOEt in ethanol (30 ml), (E)-3-(4-methylphenyl)acrylaldehyde (Compound 43, 1.1 g, 7.5 mmol) and ethyl azidoacetate (12 ml, 37.5 mmol) in EtOH (20 ml) were reacted to produce the title compound as a solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728014B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-b4766f87ad664e35965873e1b072eb02 |
| 出典メモ | uspto-grants-2010_06 |