CID 16218483 → (R)-(+)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane
反応式
[CH3:1][N:2]([C@@H:4]([C:24]1[C:28]([P:29]([C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)[C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)[CH:27][CH:26][CH:25]1)[C:5]1[CH:10]=[CH:9][CH:8]=[C:7](P(C2C=CC=CC=2)C2C=CC=CC=2)[CH:6]=1)[CH3:3].[CH:42]1[CH:46][CH:45][CH:44][CH:43]1.[Fe:47]>C(Cl)Cl>[CH3:1][N:2]([C@H:4]([C:24]1[C:28]([P:29]([C:36]2[CH:37]=[CH:38][CH:39]=[CH:40][CH:41]=2)[C:30]2[CH:31]=[CH:32][CH:33]=[CH:34][CH:35]=2)[CH:27][CH:26][CH:25]1)[C:5]1[C:10]([P:29]([C:36]2[CH:37]=[CH:38][CH:39]=[CH:40][CH:41]=2)[C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)=[CH:9][CH:8]=[CH:7][CH:6]=1)[CH3:3].[CH:42]1[CH:46][CH:45][CH:44][CH:43]1.[Fe:47]参加物
3
実験手順
Taniaphos SL-T001-1 (from Solvias, Basel, CH; 400 mg, 0.58 mmol) is placed in a round-bottom flask provided with a magnetic stirrer and the Ru starting compound (236 mg, 0.58 mmol) prepared in b) is then added. The reactants are dissolved in 10 ml of CH2Cl2 and the mixture is stirred at room temperature for three hours. The solution becomes deep red. The solvent is taken off under reduced pressure and the solid residue is washed with diethyl ether. The product is collected and dried in a high vacuum. Yield: 90%, red-orange solid, two diastereomers having a de of 75%.