Potassium Tetracyanoborate → 1-Methyl-1-octylpiperidinium tetracyanoborate

反応式

[C:1]([B-:3]([C:8]#[N:9])([C:6]#[N:7])[C:4]#[N:5])#[N:2].[K+].[Br-].[CH3:12][N+:13]1([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1>>[C:1]([B-:3]([C:8]#[N:9])([C:6]#[N:7])[C:4]#[N:5])#[N:2].[CH3:12][N+:13]1([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]1

参加物

反応物 2

HCID 23686396Potassium Tetracyanoborate

HCID 670448871-Methyl-1-octylpiperidinium bromide

生成物 1

HCID 866522271-Methyl-1-octylpiperidinium tetracyanoborate

実験手順

Analogously to Example A, 58 g of potassium tetracyanoborate are added to 100 g of 1-methyl-1-octylpiperidinium bromide, and the mixture is subjected to corresponding work-up, giving a clear, yellowish, viscous liquid.

後処理

customgiving a clear, yellowish, viscous liquid

出典と根拠

ORDレコード: ord-2772a5bec5f7403f9db3406316bef52e
出典データセット: uspto-grants-2013_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08455703B2

反応ノート

読み込み中…