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N,N'-Dimethylethylenediamine → 1-(5,6-Diphenyl-pyridin-2-yl)-propan-1-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N,N'-Dimethylethylenediamine | HCID 8070 | — |
| 反応物 | Ethyl 5,6-diphenylpyridine-2-carboxylate | HCID 14789610 | — |
| 反応物 | Triethylaluminum | HCID 16682930 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 1-(5,6-Diphenyl-pyridin-2-yl)-propan-1-one | HCID 25033167 | — |
反応手順
Following General Procedure O, ethyl 5,6-diphenylpyridine-2-carboxylate (Compound 21, 267 mg, 0.81 mmol) in toluene (5 ml), N,N′-dimethylethylenediamine (DMEDA, 85 mg, 0.97 mmol) and triethylaluminum (2.6 ml, 2.64 mmol, 1 M in hexane) were reacted to give the title compound as a yellow solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728014B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-17477629f93f4d5e92fb9a72fe881df8 |
| 出典メモ | uspto-grants-2010_06 |