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Acetic acid, azido-, ethyl ester → Methyl (2Z,4E)-2-Azido-5-(4-isopropylphenyl)penta-2,4-dienoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic acid, azido-, ethyl ester | HCID 69480 | — |
| 反応物 | 4-Isopropylcinnamaldehyde | HCID 5354897 | — |
| 反応物 | Sodium Methoxide | HCID 10942334 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Methyl (2Z,4E)-2-Azido-5-(4-isopropylphenyl)penta-2,4-dienoate | HCID 59338838 | — |
反応手順
Following General Procedure I, a 1.34 M solution of NaOMe in methanol (30 ml), (E)-3-(4-isopropylphenyl)acrylaldehyde (Compound 110, 1.4 g, 8.0 mmol) and ethyl azidoacetate (12 ml, 40.2 mmol) in MeOH (20 ml) were reacted to produce the title compound as a solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07728014B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-592b442687364ab1abccb3c7162513dc |
| 出典メモ | uspto-grants-2010_06 |