Dimethylformamide dimethyl acetal → HCID 59338827、化合物

HRID 12577

反応式

HRID 12577 の反応式
[C:1]1([C:7](=[O:16])[CH2:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CO[CH:19](OC)[N:20]([CH3:22])[CH3:21]>CN(C=O)C>[CH3:19][N:20]([CH3:22])/[CH:21]=[C:8](\[C:9]1[CH:10]=[CH:11][C:12]([CH3:15])=[CH:13][CH:14]=1)/[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)=[O:16]

参加物

4

反応物 2

HCID 78373Dimethylformamide dimethyl acetalHCID 2424732-(4-Methylphenyl)-1-phenylethan-1-one

生成物 1

HCID 59338827HCID 59338827、化合物

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

A solution of 1-phenyl-2-p-tolylethanone (2 g, 9.5 mmol) and dimethylformamide dimethylacetal (4.5 g, 38.1 mmol) in DMF (30 ml) was heated at 75° C. for 24 hours. Solvents were removed under high vacuum to obtain the title compound as a yellow oil, which was used directly in the next step without purification.

後処理

  1. customSolvents were removed under high vacuum

出典と根拠

ORDレコード
ord-6657e0aca0cb44d894f6e71979dee592
出典データセット
uspto-grants-2010_06
特許番号
US07728014B2

関連ノート

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