1-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanone → 1-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

HRID 1258525ノート

反応式

HRID 1258525 の反応式
[Br:1][C:2]1[CH:3]=[C:4]([CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1)[C:5](N(OC)C)=[O:6].[CH3:20]OC1C=C(C(=O)C)C=C(S(F)(F)(F)(F)F)C=1>>[Br:1][C:2]1[CH:3]=[C:4]([C:5](=[O:6])[CH3:20])[CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1

参加物

3

反応物 2

HCID 441831181-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanoneHCID 581374643-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide

生成物 1

HCID 581374301-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

実験手順

3-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide (1.1 g) was converted and worked up analogously to 21d). Purification by means of HPLC was not necessary. 935 mg of the title compound were obtained.

後処理

  1. customPurification by means of HPLC

出典と根拠

ORDレコード
ord-0638a360c6e0479685fe10f5a85c7df0
出典データセット
uspto-grants-2013_06
特許番号
US08466169B2

反応ノート

読み込み中…