Diethyl Ether → Trichloromethylsilane

HRID 1264180

反応式

HRID 1264180 の反応式
CCO[CH2:4][CH3:5].[Mg].[CH3:7][Si:8]([Cl:11])([Cl:10])[Cl:9].[C:12]1(Cl)[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>O>[CH3:7][Si:8]([Cl:11])([Cl:10])[Cl:9].[Si:8]([Cl:11])([C:5]1[CH:4]=[CH:14][CH:13]=[CH:12][CH:17]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH3:7]

参加物

7

反応物 4

HCID 3283Diethyl EtherHCID 6399TrichloromethylsilaneHCID 7964ChlorobenzeneHCID 5462224Magnesium

生成物 2

HCID 6399TrichloromethylsilaneHCID 67349Chloro(methyl)diphenylsilane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The ether and phenylCl are fed in a ratio of 4:1 and the magnesium is fed at a rate to sustain the reaction as monitored by the reactor temperature profile, jacket water temperature rise, and agitator motor amps. The MeSiCl3 feed is varied to obtain a coupling ratio between 0.25 and 0.90 moles of PhCl/mole of MeSiCl3 depending on the ratio of Ph2SiMeCl/PhMeSiCl2 desired. Toluene is fed in at a 3:1 ratio to the PhenylCl in ether.

後処理

  1. customthe reaction

出典と根拠

ORDレコード
ord-b4d890525b584637970382a80b33f372
出典データセット
uspto-grants-2003_04
特許番号
US06541651B1

関連ノート

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