Hydroxide → N-Butyl-N-Cyclohexylpyrrolidinium Hydroxide

HRID 1264447ノート

反応式

HRID 1264447 の反応式
[I-].[CH2:2]([N+:6]1([CH:11]2[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5].[OH-:17]>O>[OH-:17].[CH2:2]([N+:6]1([CH:11]2[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5]

参加物

4

反応物 2

HCID 961HydroxideHCID 22995118N-butyl-N-cyclohexylpyrrolidinium iodide

生成物 1

HCID 22995117N-Butyl-N-Cyclohexylpyrrolidinium Hydroxide

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

N-butyl-N-cyclohexylpyrrolidinium iodide salt (85 gm; 0.25 mol) is dissolved in 300 ml water in a 500-ml volume plastic bottle. To the solution, 300 gm of Ion-Exchange Resin-OH (BIO RAD® AH1-X8) is added and the mixture is stirred at room temperature overnight. The mixture is filtered and the solids are rinsed with additional 85 ml of water. The original filtrate and the rinse are combined and a small amount is titrated with 0.1N HCl to indicate the presence of 0.24 mol hydroxide (0.24 mol N-butyl-N-cyclohexylpyrrolidinium hydroxide) in the solution. The synthetic procedure described above is depicted below.

後処理

  1. filtrationThe mixture is filtered
  2. washthe solids are rinsed with additional 85 ml of water

出典と根拠

ORDレコード
ord-b5e176cd7c7f42d0bee014def6c69287
出典データセット
uspto-grants-2003_04
特許番号
US06544495B1

反応ノート

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