6-Iodo-1,1,1,2,2-pentafluorohexane → Ethyl 2-(5,5,6,6,6-pentafluorohexyl)-8-nonenoate

反応式

[CH2:1]([CH:8]([C:14](OCC)=O)[C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7].IC[CH2:21][CH2:22][CH2:23][C:24]([F:30])([F:29])[C:25]([F:28])([F:27])[F:26]>>[F:29][C:24]([F:30])([C:25]([F:28])([F:27])[F:26])[CH2:23][CH2:22][CH2:21][CH2:14][CH:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7])[C:9]([O:11][CH2:12][CH3:13])=[O:10]

参加物

反応物 2

HCID 120170616-Iodo-1,1,1,2,2-pentafluorohexane

HCID 18546274Diethyl 2-(6-heptenyl)malonate

生成物 1

HCID 18546257Ethyl 2-(5,5,6,6,6-pentafluorohexyl)-8-nonenoate

実験手順

Starting with diethyl 2-(6-heptenyl)malonate and the 1-iodo-5,5,6,6,6-pentafluorohexane prepared in Example 2, the same procedure as shown in Example 5 was repeated to give ethyl 2-(5,5,6,6,6-pentafluorohexyl)-8-nonenoate.

出典と根拠

ORDレコード: ord-02487c357dcb4ea68218b067ad104f04
出典データセット: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06552068B1

反応ノート

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