Water → 1,3-Benzenedicarboxylic acid, 2-hydroxy- (9CI)

HRID 1268227ノート

反応式

HRID 1268227 の反応式
C[O:2][C:3]1[C:11]([C:12]([OH:14])=[O:13])=[CH:10][CH:9]=[CH:8][C:4]=1[C:5]([OH:7])=[O:6].O>I>[OH:2][C:3]1[C:11]([C:12]([OH:14])=[O:13])=[CH:10][CH:9]=[CH:8][C:4]=1[C:5]([OH:7])=[O:6]

参加物

4

反応物 2

HCID 962WaterHCID 45588112-Methoxyisophthalic acid

生成物 1

HCID 118121,3-Benzenedicarboxylic acid, 2-hydroxy- (9CI)収率 96.9%

試薬・触媒・溶媒 1

HCID 24841Hydrogen iodide溶媒

実験手順

A solution of 2-methoxyisophthalic acid (1.0 g) in 55% hydriodic acid (10 ml) was heated at 80° C. for 1 hour. The reaction mixture was poured into iced water and the precipitate was collected by filtration to give the desired compound (0.9 g, yield 95%) as a pale yellow solid.

後処理

  1. filtrationthe precipitate was collected by filtration

出典と根拠

ORDレコード
ord-8ee74bf8a9f14c3889bdec5d716637ae
出典データセット
uspto-grants-2003_04
特許番号
US06555556B1

反応ノート

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