Bromine → HCID 20286562、化合物

HRID 126878

反応式

HRID 126878 の反応式
[Cl:1][CH2:2][C:3]([CH3:16])([CH3:15])[C:4](=[O:14])[CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([Cl:13])=[CH:9][CH:8]=1.[Br:17]Br>C(Cl)(Cl)(Cl)Cl>[Br:17][CH:5]([O:6][C:7]1[CH:8]=[CH:9][C:10]([Cl:13])=[CH:11][CH:12]=1)[C:4](=[O:14])[C:3]([CH3:16])([CH3:15])[CH2:2][Cl:1]

参加物

4

反応物 2

HCID 24408BromineHCID 201382951-(p-Chlorophenoxy)-3,3-dimethyl-4-chloro-2-butanone

生成物 1

HCID 20286562HCID 20286562、化合物収率 7,890.2%

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

210 g (0.81 mol) of 4-chloro-1-(4-chlorophenoxy)-3,3-dimethyl-butan-2-one were dissolved in 1,000 ml of carbon tetrachloride. 41 ml (0.01 mol) of bromine were added dropwise at room temperature at a rate such that it was continuously consumed. The mixture was then stirred at room temperature for 30 minutes. After distilling off the solvent in vacuo, 268.3 g (98% of theory) of crude 1-bromo-4-chloro-1-(4-chlorophenoxy)-3,3-dimethyl-butan-2-one were obtained and were further reacted directly. ##STR13##

後処理

  1. customwas continuously consumed
  2. distillationAfter distilling off the solvent in vacuo

出典と根拠

ORDレコード
ord-f3bd0bedf99047ddbf3f89a21051da3e
出典データセット
uspto-grants-1981_03
特許番号
US04254132

関連ノート

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