Tetrafluoroboric acid → Diphenyliodonium Tetrafluoroborate

HRID 127657ノート

反応式

HRID 127657 の反応式
S(=O)(=O)(O)[O-].[C:6]1([I+:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[F:19][B-:20]([F:23])([F:22])[F:21].[H+].P(O)(O)O.[Cl-].C1([I+]C2C=CC=CC=2)C=CC=CC=1>F[B-](F)(F)F.[Ag+].O>[F:19][B-:20]([F:23])([F:22])[F:21].[C:13]1([I+:12][C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

参加物

7

反応物 4

HCID 28118Tetrafluoroboric acidHCID 73870Diphenyliodonium chlorideHCID 107909Phosphorous acidHCID 170803Iodonium, diphenyl-, sulfate (1:1)

生成物 1

HCID 11122160Diphenyliodonium Tetrafluoroborate

試薬・触媒・溶媒 2

HCID 159722Silver tetrafluoroborate触媒HCID 962Water溶媒

実験手順

The aromatic iodonium complex salts may be prepared by metathesis of corresponding aromatic iodonium simple salts (such as, for example, the diphenyliodonium bisulfate) in accordance with the teachings of Beringer, et al., J. Am. Chem. Soc. 81, 342 (1959). Thus, for examples, the complex salt diphenyliodonium tetrafluoroborate is prepared by the addition of 60° C. of an aqueous solution containing 29.2 g. (150 millimoles) silver fluoroborate, 2 g. fluoroboric acid, and 0.5 g. phosphorous acid in about 30 ml. of water to a solution of 44 g. (139 millimoles) of diphenyliodonium chloride. The silver halide that precipitates is filtered off and the filtrate concentrated to yield diphenyliodonium fluoroborate which may be purified by recrystallization.

後処理

  1. customis prepared by the addition of 60° C. of an aqueous solution
  2. additioncontaining 29.2 g
  3. customThe silver halide that precipitates
  4. filtrationis filtered off
  5. concentrationthe filtrate concentrated

出典と根拠

ORDレコード
ord-6141855c4d57457e991d9ba1d1b3b1e9
出典データセット
uspto-grants-1981_03
特許番号
US04256828

反応ノート

読み込み中…