1-Butanol → 1-Butene, 3-butoxy-

反応式

[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[CH2:6]=[CH:7][CH:8]=[CH2:9]>>[CH2:1]([O:5][CH:8]([CH3:9])[CH:7]=[CH2:6])[CH2:2][CH2:3][CH3:4].[CH2:1]([O:5][CH2:6][CH:7]=[CH:8][CH3:9])[CH2:2][CH2:3][CH3:4]

参加物

反応物 2

HCID 2631-Butanol

HCID 78451,3-Butadiene

生成物 2

HCID 5437051-Butene, 3-butoxy-

HCID 5439041-Butoxybut-2-ene

実験手順

0.90 mol of n-butanol and 0.88 mol of 1,3-butadiene were reacted in a manner similar to Example 8b) in the presence of 5 g of the zeolite in the H+ form, prepared according to Example 8a). At a conversion of 40.0%, 3-butoxybut-1-ene was formed with a selectivity of 42.5% and 1-butoxybut-2-ene with a selectivity of 16.5%.

後処理

customprepared

出典と根拠

ORDレコード: ord-b909ab406e1a4450ade8cb6dc3e03805
出典データセット: uspto-grants-2000_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06166265

反応ノート

読み込み中…