Bromine → 4-(Bromomethyl)-2-fluoro-1,1′-biphenyl
反応式
[Br:1]Br.[F:3][C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[CH:6][C:5]=1[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>C(Cl)(Cl)(Cl)Cl>[F:3][C:4]1[CH:9]=[C:8]([CH2:10][Br:1])[CH:7]=[CH:6][C:5]=1[C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1参加物
4
実験手順
In this instance one equivalent of Br2 was added dropwise to a refluxing solution of 2-fluoro-4-methylbiphenyl and CCl4 while being irradiated with a sunlamp. NMR analysis showed the ratio of starting material:monobromide:dibromide to be 21:67:12.
後処理
- customwhile being irradiated with a sunlamp
出典と根拠
- ORDレコード
- ord-51da4e8bee8d4704add9170ffa9141b9
- 出典データセット
- uspto-grants-1981_07
- 特許番号
- US04278516
反応ノート
読み込み中…