Hydrochloric Acid → HCID 552076、化合物

HRID 1278090

反応式

HRID 1278090 の反応式
[C:1]([O:11][CH2:12][CH3:13])(=[O:10])[CH:2]([CH2:4][C:5]([O:7][CH2:8][CH3:9])=[O:6])[OH:3].Cl.[CH:15]([O:17][CH2:18][CH3:19])=[CH2:16]>>[CH2:15]([O:17][CH:18]([O:3][CH:2]([CH2:4][C:5]([O:7][CH2:8][CH3:9])=[O:6])[C:1]([O:11][CH2:12][CH3:13])=[O:10])[CH3:19])[CH3:16]

参加物

4

反応物 3

HCID 313Hydrochloric AcidHCID 8023Ethyl vinyl etherHCID 24197Diethyl malate

生成物 1

HCID 552076HCID 552076、化合物

実験手順

A mixture of 19 g. diethyl malate and 0.1 g. of 36% hydrochloric acid was added to a 50 ml. round-bottom flask equipped with an addition funnel, static nitrogen head, condensor, heating mantle, thermometer, and magnetic stirrer. Ethyl vinyl ether was then added, dropwise, at 41° to 43° C. over a one-hour period and quenched with 0.4 g. of solid sodium carbonate. Distillation was performed directly on the mixture (short path column):

後処理

  1. additionA mixture of 19 g
  2. customround-bottom flask equipped with an addition funnel
  3. temperaturestatic nitrogen head, condensor, heating mantle
  4. waitdropwise, at 41° to 43° C. over a one-hour period
  5. customquenched with 0.4 g
  6. distillationDistillation

出典と根拠

ORDレコード
ord-03a0d5d11dcb4ebe840566a809e39380
出典データセット
uspto-grants-1981_07
特許番号
US04280011

関連ノート

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