Trimethyloxonium hexachlorantimonate → 2-Methyl-3,4,5-trichloroisothiazolium hexachloroantimonate

反応式

[Cl:1][Sb-:2]([Cl:7])([Cl:6])([Cl:5])([Cl:4])[Cl:3].[CH3:8][O+](C)C.[Cl:12][C:13]1[S:17][N:16]=[C:15]([Cl:18])[C:14]=1[Cl:19]>>[Cl:1][Sb-:2]([Cl:7])([Cl:6])([Cl:5])([Cl:4])[Cl:3].[CH3:8][N+:16]1[S:17][C:13]([Cl:12])=[C:14]([Cl:19])[C:15]=1[Cl:18]

参加物

反応物 2

HCID 150258Trimethyloxonium hexachlorantimonate

HCID 12333154Trichloroisothiazole

生成物 1

HCID 166957382-Methyl-3,4,5-trichloroisothiazolium hexachloroantimonate収率 73%

実験手順

Trichloroisothiazole (10 ml) and trimethyloxonium hexachloroantimonate (7.9 g, 0.02 mol) were heated at 90° for 30 min. After cooling either (150 ml) was added and the solid collected to yield 7.8 g (73%) of product, mp >240. Spectral data (NMR & IR) were consistent with the assigned structure.

後処理

temperatureAfter cooling either (150 ml)
additionwas added
customthe solid collected

出典と根拠

ORDレコード: ord-37f66aeceb484dcd8d059bf7bae3ae26
出典データセット: uspto-grants-1981_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04281136

反応ノート

読み込み中…

参加物