Triethyl phosphite → HCID 54402546、化合物

反応式

Cl[CH:2]([O:5][CH3:6])[CH2:3][Cl:4].[P:7]([O:14]CC)([O:11][CH2:12][CH3:13])[O:8][CH2:9][CH3:10]>>[CH2:9]([O:8][P:7]([CH:2]([O:5][CH3:6])[CH2:3][Cl:4])(=[O:14])[O:11][CH2:12][CH3:13])[CH3:10]

参加物

反応物 2

HCID 31215Triethyl phosphite

HCID 162049Ethane, 1,2-dichloro-1-methoxy-

生成物 1

HCID 54402546HCID 54402546、化合物収率 57.8%

実験手順

0.9 mole of methyl 1,2-dichloroethyl ether was added dropwise to 1 mole of triethyl phosphite at 120° C., under a N2 atmosphere. After a reaction time of 8 hours, the mixture was fractionated. 120 g of 1-methoxy-2-chloroethane-phosphonic acid diethyl ester were obtained.

後処理

customAfter a reaction time of 8 hours

出典と根拠

ORDレコード: ord-a922a4b4c5f14e849b0a4e4023bb40db
出典データセット: uspto-grants-1981_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04257987

反応ノート

読み込み中…