化工社化工社 化学情報印刷レポート · 研究参考用
Myrcene → (Z)-2,6-dimethyloct-2-ene-1,8-diol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Myrcene | HCID 31253 | — |
| 反応物 | Sodium Acetate | HCID 517045 | — |
| 反応物 | Neryl acetate | HCID 1549025 | — |
| 反応物 | Calcium Hydroxide | HCID 6093208 | — |
| 反応物 | Dichloro di-methyloctene | HCID 20571628 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | (Z)-2,6-dimethyloct-2-ene-1,8-diol | HCID 77134639 | — |
反応手順
Prod.: (many methods) e.g. from Myrcene, via Myrcene dihydrochloride to Dichloro di-methyloctene. This is converted to Chloro di-hydrogeranyl acetate (and-neryl acetate) with Sodium Acetate in Benzene in presence of Triethylamine. The acetates are saponified with Calcium hydroxide to yield Hydroxycitronellol, from which the aldehyde is prepared by oxidation.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04258727 |
| 出典データセット | uspto-grants-1981_03 |
| ORD ID | ord-556bbc3a328e454ab039bc372f2aeabf |
| 出典メモ | uspto-grants-1981_03 |