2,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexene → 2,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

HRID 1283346ノート

反応式

HRID 1283346 の反応式
CC1CCCC(C)(C)C=1C(O)CC=C.[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:23])([CH3:22])[C:17]=1[CH:24]([OH:29])[CH2:25][C:26]([CH3:28])=[CH2:27]>>[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:22])([CH3:23])[C:17]=1[C:24](=[O:29])[CH2:25][C:26]([CH3:28])=[CH2:27]

参加物

3

反応物 2

HCID 124203212,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexeneHCID 233380582,6,6-Trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene

生成物 1

HCID 233380842,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

実験手順

By replacing hereabove 2,6,6-trimethyl-1-[1-hydroxy-3-butenyl]-1-cyclohexene with 2,6,6-trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene (nD20 = 1.4939; d420 = 0.9270), 2,6,6-trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene was obtained; ndD20 = 1.4862; d420 = 0.9307.

出典と根拠

ORDレコード
ord-8124431facd84e38bd14608a1d4f2840
出典データセット
uspto-grants-1976_08
特許番号
US03975310

反応ノート

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