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Dichloromethane → HCID 20499026、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Methyl 2-hydroxybutanoate | HCID 520445 | — |
| 反応物 | 4-(Cyclohex-3-enylmethylamino)hydrocinnamoyl chloride hydrochloride | HCID 20498938 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | HCID 20499026 | HCID 20499026 | — |
反応手順
To a solution of 10.0 g. 4-(cyclohex-3-enylmethylamino)hydrocinnamoyl chloride hydrochloride in 200 ml. methylene chloride is added dropwise a solution of 3 g. methyl 2-hydroxybutyrate and 5 g. triethylamine in 100 ml. ether. After 17 hours stirring at room temperature, the precipitate is collected and washed with several portions of ether. The ether solution is washed with water, dried and evaporated to yield 1-(methoxycarbonyl)propyl 4-(cyclohex-3-enylmethylamino)hydrocinnamate as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04259352 |
| 出典データセット | uspto-grants-1981_03 |
| ORD ID | ord-ea03a9192e7447e3bb69d05468adc2b6 |
| 出典メモ | uspto-grants-1981_03 |