Potassium Hydroxide → N,N'-bis(4-anilinophenyl)-4,10-dithia-7-oxatridecanediamide

HRID 1283478

反応式

HRID 1283478 の反応式
[NH:1]([C:8]1[CH:13]=[CH:12][C:11]([NH:14][C:15](=[O:18])[CH:16]=[CH2:17])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[SH:19][CH2:20][CH2:21][O:22][CH2:23][CH2:24][SH:25].[OH-:26].[K+]>C(O)C>[NH:1]([C:8]1[CH:9]=[CH:10][C:11]([NH:14][C:15](=[O:18])[CH2:16][CH2:17][S:19][CH2:20][CH2:21][O:22][CH2:23][CH2:24][S:25][CH2:17][CH2:16][C:15]([NH:14][C:11]2[CH:12]=[CH:13][C:8]([NH:1][C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)=[CH:9][CH:10]=2)=[O:26])=[CH:12][CH:13]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 750732,2'-OxybisethanethiolHCID 22601822N-(4-Anilinophenyl)prop-2-enamide

生成物 1

HCID 21518143N,N'-bis(4-anilinophenyl)-4,10-dithia-7-oxatridecanediamide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒2 回

実験手順

To a suspension of 100 grams of N-(4-anilinophenyl) acrylamide in 1200 milliliters of ethanol was added 29 grams of 2-mercaptoethyl ether. A solution of 5 grams of potassium hydroxide in 50 milliliters of ethanol was added at 20°C. Within 5 minutes the temperature began to rise, reaching a maximum of 29°C. after about 15 minutes. As the temperature began to rise, product began to precipitate. The reaction mixture was stirred for 1 hour and the solid product was then filtered off and allowed to dry. There was obtained 123 grams (95 percent of theory) of product which melted at 154°-156° C.

後処理

  1. customa maximum of 29°C.
  2. customafter about 15 minutes
  3. customto precipitate
  4. filtrationthe solid product was then filtered off
  5. customto dry
  6. customThere was obtained 123 grams (95 percent of theory) of product which melted at 154°-156° C.

出典と根拠

ORDレコード
ord-6b2569ff8300415cb0bed72a5c48416d
出典データセット
uspto-grants-1976_08
特許番号
US03975414

関連ノート

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