Potassium Hydroxide → N,N'-bis(4-anilinophenyl)-4,7,10-trithiatridecanediamide

HRID 1283479

反応式

HRID 1283479 の反応式
[NH:1]([C:8]1[CH:13]=[CH:12][C:11]([NH:14][C:15](=[O:18])[CH:16]=[CH2:17])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[SH:19][CH2:20][CH2:21][S:22][CH2:23][CH2:24][SH:25].[OH-:26].[K+]>C(O)C>[NH:1]([C:8]1[CH:9]=[CH:10][C:11]([NH:14][C:15](=[O:18])[CH2:16][CH2:17][S:19][CH2:20][CH2:21][S:22][CH2:23][CH2:24][S:25][CH2:17][CH2:16][C:15]([NH:14][C:11]2[CH:12]=[CH:13][C:8]([NH:1][C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)=[CH:9][CH:10]=2)=[O:26])=[CH:12][CH:13]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 77117Bis(2-mercaptoethyl) sulfideHCID 22601822N-(4-Anilinophenyl)prop-2-enamide

生成物 1

HCID 21518148N,N'-bis(4-anilinophenyl)-4,7,10-trithiatridecanediamide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒2 回

実験手順

To a suspension of 200 grams of N-(4-anilinophenyl)acrylamide in 2450 milliliters of ethanol was added 64.8 grams of 2-mercaptoethyl sulfide. A solution of 5 grams of potassium hydroxide in 50 milliliters of ethanol was then added at 20°C. Within 5 minutes the temperature began to rise, reaching a maximum of 31°C. after about 15 minutes. As the temperature began to rise, product began to precipitate. The reaction mixture was stirred for 1 hour and the solid product was then filtered off and allowed to dry. There was obtained 231.7 grams (87.5 percent of theory) of product which melted at 195.5° to 197.5°C.

後処理

  1. customa maximum of 31°C.
  2. customafter about 15 minutes
  3. customto precipitate
  4. filtrationthe solid product was then filtered off
  5. customto dry
  6. customThere was obtained 231.7 grams (87.5 percent of theory) of product which melted at 195.5° to 197.5°C.

出典と根拠

ORDレコード
ord-9c148834c0ec4fb5baacdb2542dcae83
出典データセット
uspto-grants-1976_08
特許番号
US03975414

関連ノート

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