Potassium Hydroxide → N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

HRID 1283480

反応式

HRID 1283480 の反応式
[SH:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][SH:7].[NH:8]([C:15]1[CH:20]=[CH:19][C:18]([NH:21][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24])=[CH:17][CH:16]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[OH-:27].[K+]>C(O)C>[NH:8]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22](=[O:26])[CH:23]([CH3:25])[CH2:24][S:1][CH2:2][CH2:3][S:4][CH2:5][CH2:6][S:7][CH2:24][CH:23]([CH3:25])[C:22]([NH:21][C:18]2[CH:19]=[CH:20][C:15]([NH:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:16][CH:17]=2)=[O:27])=[CH:19][CH:20]=1)[C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 77117Bis(2-mercaptoethyl) sulfideHCID 1624682-Propenamide, 2-methyl-N-(4-(phenylamino)phenyl)-

生成物 1

HCID 21518137N,N'-bis(4-anilinophenyl)-2,12-dimethyl-4,7,10-trithiatridecanediamide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒2 回

反応条件

温度
50 °C

実験手順

Sixty-one grams of 2-mercaptoethyl sulfide was added to a solution of 200 grams of N-(4-anilinophenyl) methacrylamide in 2450 milliliters of ethanol. A solution of 5 grams of potassium hydroxide in 50 milliliters of ethanol was then added, and the mixture was heated at 50°C. for 5 hours. Product began to precipitate after about 2 hours. The mixture was then allowed to cool to room temperature and the solid product was filtered off. The product, after drying, weighed 231.5 grams (89 percent of theory) and melted at 131° to 133.5°C.

後処理

  1. customto precipitate after about 2 hours
  2. temperatureto cool to room temperature
  3. filtrationthe solid product was filtered off
  4. customThe product, after drying

出典と根拠

ORDレコード
ord-2359960700c54f4585be3a0945ea3e63
出典データセット
uspto-grants-1976_08
特許番号
US03975414

関連ノート

読み込み中…