Ammonium → HCID 178491260、化合物

HRID 128423

反応式

HRID 128423 の反応式
[NH4+:1].[Cl:2][C:3]1[CH:4]=[C:5]([CH:24]=[CH:25][C:26]=1[Cl:27])[CH:6]=[CH:7][S:8]([N:11]=[C:12](Cl)[C:13]1[CH:18]=[CH:17][C:16]([O:19][CH3:20])=[C:15]([O:21][CH3:22])[CH:14]=1)(=[O:10])=[O:9]>C1C=CC=CC=1>[Cl:2][C:3]1[CH:4]=[C:5]([CH:24]=[CH:25][C:26]=1[Cl:27])[CH:6]=[CH:7][S:8]([NH:11][C:12](=[NH:1])[C:13]1[CH:18]=[CH:17][C:16]([O:19][CH3:20])=[C:15]([O:21][CH3:22])[CH:14]=1)(=[O:10])=[O:9]

参加物

4

反応物 2

HCID 223AmmoniumHCID 54107493N-(3,4-dichlorostyrylsulfonyl)-3,4-dimethoxybenzimidoyl chloride

生成物 1

HCID 178491260HCID 178491260、化合物収率 96%

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

Ammonium gas is bubbled through a solution of N-(3,4-dichlorostyrylsulfonyl)-3,4-dimethoxybenzimidoyl chloride (8.7 g., 0.02 mole) in 100 ml. of dry benzene for a period of 1 hr. The solvent evaporated under reduced pressure and the solid residue stirred with 50 ml. of water and filtered affords 8.0 g. (96% yield) of N-(3,4-DICHLOROSTYRYLSULFONYL)-3,4-DIMETHOXYBENZAMIDINE, m.p. 205°-210° C. A sample crystallized from acetonitrile has a melting point of 208°-211° C.

後処理

  1. customThe solvent evaporated under reduced pressure
  2. filtrationof water and filtered
  3. customaffords 8.0 g

出典と根拠

ORDレコード
ord-139fa0e60a3f4a23bb132a56653dd96e
出典データセット
uspto-grants-1981_03
特許番号
US04259482

関連ノート

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