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Phenol → Cholesterol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phenol | HCID 996 | — |
| 反応物 | 4-Aminoantipyrine | HCID 2151 | — |
| 反応物 | X 100 | HCID 19153 | — |
| 反応物 | Potassium Phosphate, Dibasic | HCID 24450 | — |
| 反応物 | Monobasic potassium phosphate | HCID 516951 | — |
| 反応物 | sodium (4R)-4-[(3R,5S,7R,8R,9R,10S,12S,13R,14R,17R)-3,7,12-trihydroxy-8,10,13-trimethyl-1,2,3,4,5,6,7,9,11,12,14,15,16,17-tetradecahydrocyclopenta[a]phenanthren-17-yl]pentanoate | HCID 44582063 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Cholesterol | HCID 5997 | — |
反応手順
In a 250 ml flask, a reaction mixture (designated "mixture A") was prepared by adding to 90 ml of distilled water the following: 1.497 g (KH2PO4 ; 1.568 g K2HPO4 ; 0.431 g. sodium cholate; 1.05 ml of a 25% solution of an alkylphenoxypolyethoxy ethanol, commercially available from Rohm and Haas Co., Philadelphia, Pa., under the trade designation Triton X-100; 0.0169 g 4-aminoantipyrine (used as a chromogen); and 0.145 ml phenol (10 M). Sufficient distilled water was added to make a final volume of 100 ml.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04259440 |
| 出典データセット | uspto-grants-1981_03 |
| ORD ID | ord-ed5a26d05eb249218272871db3a6f1ae |
| 出典メモ | uspto-grants-1981_03 |