Ethyl 2-butyryl-3-ethoxyacrylate → HCID 178450502、化合物

HRID 128608

反応式

HRID 128608 の反応式
C(O[CH:4]=[C:5]([C:11](=[O:15])[CH2:12][CH2:13][CH3:14])[C:6]([O:8][CH2:9][CH3:10])=[O:7])C.[CH2:16]([O:18][C:19]1[CH:20]=[CH:21][C:22]([NH2:26])=[N:23][C:24]=1[CH3:25])[CH3:17]>>[CH2:16]([O:18][C:19]1[CH:20]=[CH:21][C:22]([NH:26][CH:4]=[C:5]([C:11](=[O:15])[CH2:12][CH2:13][CH3:14])[C:6]([O:8][CH2:9][CH3:10])=[O:7])=[N:23][C:24]=1[CH3:25])[CH3:17]

参加物

3

反応物 2

HCID 3359484Ethyl 2-butyryl-3-ethoxyacrylateHCID 128750175-Ethoxy-6-methylpyridin-2-amine

生成物 1

HCID 178450502HCID 178450502、化合物

実験手順

Ethyl 2-(ethoxymethylene)-3-oxohexanoate (22.4 g) was added to a suspension of 5-ethoxy-6-methylpyridin-2-amine (14.9 g) in IMS (50 ml). After the initial exotherm had subsided IMS (100 ml) was added and the mixture boiled under reflux until a solution was obtained. This solution was cooled and filtered to give ethyl 2-(5-ethoxy-6-methylpyrid-2-ylaminomethylene)-3-oxohexanoate, m.p. 117°-120° C.

後処理

  1. additionwas added
  2. temperatureunder reflux until a solution
  3. customwas obtained
  4. temperatureThis solution was cooled
  5. filtrationfiltered

出典と根拠

ORDレコード
ord-bfd9709289484cfd9994972d7ffdb45d
出典データセット
uspto-grants-1995_11
特許番号
US05464781

関連ノート

読み込み中…