2,4-Dimethyl-1,3-Phenylenediamine Dihydrochloride → Indoaniline

HRID 1287210

反応式

HRID 1287210 の反応式
Cl.Cl.C[C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[C:6](C)[C:5]=1N.C[C:14]1[C:15](=[N:22]Cl)[C:16](C)=[CH:17][C:18](=[O:20])[CH:19]=1>C(O)(C)C>[CH:16]1[C:15](=[N:22][C:4]2[CH:5]=[CH:6][C:7]([NH2:10])=[CH:8][CH:9]=2)[CH:14]=[CH:19][C:18](=[O:20])[CH:17]=1

参加物

4

反応物 2

HCID 211907462,4-Dimethyl-1,3-Phenylenediamine DihydrochlorideHCID 21539672HCID 21539672、化合物

生成物 1

HCID 24748760Indoaniline収率 100.9%

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

実験手順

0.003 mole (0.627 g) of 1,3-dimethyl 2,4-diamino benzene dihydrochloride is dissolved in 11 cc of 0.82 N soda solution. To this solution, cooled to 0°, there is added 0.002 mole (0.339 g) of 2,6-dimethyl N-chlorobenzoquinone monoimine in solution in 6 cc of isopropanol. The reaction mixture rapidly turns blue. It is allowed to stand for one hour at 0.20. Then 0.400 g of the above indoaniline is isolated in the form of beautiful green flakes with golden glints by filtering. After washing with water and extended vacuum drying, the product melts at 196° (no drop of melting point is observed when used in mixture with the product prepared according to Example 22).

後処理

  1. temperatureTo this solution, cooled to 0°

出典と根拠

ORDレコード
ord-ba18645b759a483abb155f9c3c70784f
出典データセット
uspto-grants-1976_10
特許番号
US03984402

関連ノート

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