化工社化工社 化学情報印刷レポート · 研究参考用
2-Naphthol → Ethyl 6-(2-naphthyloxy)hexanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Naphthol | HCID 8663 | — |
| 反応物 | Ethyl 6-bromohexanoate | HCID 117544 | — |
| 反応物 | Sodium | HCID 5360545 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Ethyl 6-(2-naphthyloxy)hexanoate | HCID 19375098 | — |
反応手順
Ethyl 6-bromohexanoate and the sodium salt of 2-naphthol are reacted in DMF at 70° to provide ethyl 6-(2-naphthyloxy)hexanoate, which after the usual workup is reduced with lithium aluminum hydride in THF to provide 6-(2-naphthyloxy)hexanol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05464865 |
| 出典データセット | uspto-grants-1995_11 |
| ORD ID | ord-cbe01735c94b4625940887766daee71c |
| 出典メモ | uspto-grants-1995_11 |