HCID 18925402、化合物 → HCID 18925409、化合物

反応式

[N+](C1C=CSC=1C1C=CC(Cl)=CC=1)([O-])=O.[N+:16]([C:19]1[CH:23]=[CH:22][S:21][C:20]=1[C:24]1[CH:29]=[CH:28][C:27]([CH3:30])=[CH:26][CH:25]=1)([O-])=O>>[NH2:16][C:19]1[CH:23]=[CH:22][S:21][C:20]=1[C:24]1[CH:29]=[CH:28][C:27]([CH3:30])=[CH:26][CH:25]=1

参加物

反応物 2

HCID 18925402HCID 18925402、化合物

HCID 18925412HCID 18925412、化合物

生成物 1

HCID 18925409HCID 18925409、化合物収率 68%

実験手順

The same procedures as described in Example 3 were carried out except that 3-nitro-2-(4-chlorophenyl)thiophene was replaced by 3-nitro-2-(4-tolyl)thiophene. The yield was 68%. 1H-NMR(CDCl3, δ value):2.37(3H, s), 3.79(2H, brs), 6.54(d, J=5.1), 7.09(1H, d, J=5.1), 7.22(2H, d, J=8.1), 7.41(2H, d, J=8.1)

出典と根拠

ORDレコード: ord-15f838ef91a945aba7951adad6cf8a1b
出典データセット: uspto-grants-1998_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05747518

反応ノート

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