Methanol, 1,1-diethoxy-, 1-acetate → 2-[(Dimethylaminomethylidene)amino]-6-methyl-1,2,4-triazolo[1,5-a]-1,3,5-triazine-7(6H)-thione

HRID 1289798ノート

反応式

HRID 1289798 の反応式
[NH2:1][C:2]1[N:6]([C:7]([NH:9][CH3:10])=[S:8])[N:5]=[C:4]([N:11]=[CH:12][N:13]([CH3:15])[CH3:14])[N:3]=1.[C:16](OC(OCC)OCC)(=O)C>>[CH3:15][N:13]([CH:12]=[N:11][C:4]1[N:3]=[C:2]2[N:1]=[CH:10][N:9]([CH3:16])[C:7](=[S:8])[N:6]2[N:5]=1)[CH3:14]

参加物

3

反応物 2

HCID 84166Methanol, 1,1-diethoxy-, 1-acetateHCID 867525445-Amino-3-[(dimethylaminomethylidene)amino]-1-[methylamino(thiocarbonyl)]-1H-1,2,4-triazole

生成物 1

HCID 867525462-[(Dimethylaminomethylidene)amino]-6-methyl-1,2,4-triazolo[1,5-a]-1,3,5-triazine-7(6H)-thione収率 56%

実験手順

The synthesis method of Example 55 was applied. The compound (486 mg) obtained in Example 33 and diethoxymethyl acetate (5 ml) were used as reagents. The mixture was reacted at 95° C. for 2 hours to give 282 mg of pale-brown crystals (yield 56%).

後処理

  1. customThe synthesis method of Example 55
  2. customThe mixture was reacted at 95° C. for 2 hours

出典と根拠

ORDレコード
ord-691622487f6947b78fa0f9de9897e094
出典データセット
uspto-grants-1998_05
特許番号
US05750545

反応ノート

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