Toluene → 1-Ethenyl-4-methylbenzene

HRID 129540

反応式

HRID 129540 の反応式
C[Al]1[CH2:7][CH2:6][CH2:5][CH2:4]O1.[C:8]1(C)[CH:13]=[CH:12]C=[CH:10][CH:9]=1>C([Ti](CC1C=CC=CC=1)(CC1C=CC=CC=1)CC1C=CC=CC=1)C1C=CC=CC=1>[CH3:4][C:5]1[CH:10]=[CH:9][C:8]([CH:13]=[CH2:12])=[CH:7][CH:6]=1

参加物

4

反応物 2

HCID 1140TolueneHCID 23511181Methylalumoxane

生成物 1

HCID 121611-Ethenyl-4-methylbenzene

試薬・触媒・溶媒 1

HCID 178420299HCID 178420299、化合物触媒

実験手順

A syndiotactic poly-p-methyl-styrene in powder form is prepared according to the method described in Macromolecules, 1989, 22, 104. p-Methyl-styrene (0.5 mmoles) is polymerized in toluene (59 ml) at 50° C. for 24 hours, in the presence of tetrabenzyltitanium (5·10 moles) and methylalumoxane (0.3 g); 8.5 g of s-PpMS are obtained. A film about 100 microns thick is produced by compression molding at a pressure of 2 Kg/cm2 and at a temperature of 230° C. An amorphous film is thus obtained.

後処理

  1. custom8.5 g of s-PpMS are obtained
  2. customA film about 100 microns thick is produced by compression molding at a pressure of 2 Kg/cm2 and at a temperature of 230° C
  3. customAn amorphous film is thus obtained

出典と根拠

ORDレコード
ord-0d799e0068c248149064b0a182c8fd07
出典データセット
uspto-grants-1995_11
特許番号
US05468823

関連ノート

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