化工社化工社 化学情報印刷レポート · 研究参考用
Isoprene → 3-Cyclohexene-1-methanol, 4-methyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isoprene | HCID 6557 | — |
| 反応物 | Acrolein | HCID 7847 | — |
| 生成物 | 3-Cyclohexene-1-methanol, 4-methyl- | HCID 564672 | — |
反応手順
According to the well known Diels-Alder Reaction, using isoprene and acrolein as raw materials, 4-methyl-3-cyclohexenyl aldehyde was synthesized. The reaction was conducted under the conditions described in the literary documents of J. Amer, Chem. Soc., 119, 15, 1997, 3507–3512; and Tetrahedron Lett., 40, 32, 1999, 5817–5822. Subsequently, the compound was reduced to obtain 4-methyl-3-cyclohexenylmethanol at a high yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07244473B2 |
| 出典データセット | uspto-grants-2007_07 |
| ORD ID | ord-a2df1a5bfa5e48be8451605455c85220 |
| 出典メモ | uspto-grants-2007_07 |