Methylamine → 828242-89-3

HRID 1295736ノート

反応式

HRID 1295736 の反応式
[CH3:1][S:2][CH2:3][O:4][C:5]1[CH:6]=[C:7]([CH:10]=[CH:11][CH:12]=1)[CH:8]=O.[CH3:13][NH2:14]>CCO>[CH3:13][N:14]=[CH:8][C:7]1[CH:10]=[CH:11][CH:12]=[C:5]([O:4][CH2:3][S:2][CH3:1])[CH:6]=1

参加物

4

反応物 2

HCID 6329MethylamineHCID 714171123-[(Methylsulfanyl)methoxy]benzaldehyde

生成物 1

HCID 69507905828242-89-3

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

反応条件

温度
40 °C

実験手順

3-Methylsulfanylmethoxy-benzaldehyde from step 1 (3.309 g, 18.16 mmol) was dissolved in EtOH (9 mL). MeNH2 (2.55 mL, 40% in H2O) was added and the mixture was heated to 40° C. for 30 min. Upon cooling, the mixture was concentrated in vacuo. The aqueous residue was diluted with isopropanol and then concentrated in vacuo. This was repeated twice more giving 3.55 g (quant) of a pale yellow oil.

後処理

  1. temperatureUpon cooling
  2. concentrationthe mixture was concentrated in vacuo
  3. additionThe aqueous residue was diluted with isopropanol
  4. concentrationconcentrated in vacuo
  5. customThis was repeated twice more giving 3.55 g (quant) of a pale yellow oil

出典と根拠

ORDレコード
ord-1d7ba7712bc54ebab51e00a99045115a
出典データセット
uspto-grants-2007_07
特許番号
US07244738B2

反応ノート

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