Diphenyliodonium chloride → Diphenyliodonium tetrakis(pentafluorophenyl)borate

HRID 129651

反応式

HRID 129651 の反応式
[Cl-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[F:15][C:16]1[C:21]([B-:22]([C:45]2[C:50]([F:51])=[C:49]([F:52])[C:48]([F:53])=[C:47]([F:54])[C:46]=2[F:55])([C:34]2[C:39]([F:40])=[C:38]([F:41])[C:37]([F:42])=[C:36]([F:43])[C:35]=2[F:44])[C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])=[C:20]([F:56])[C:19]([F:57])=[C:18]([F:58])[C:17]=1[F:59].[Li+]>O>[F:51][C:50]1[C:45]([B-:22]([C:23]2[C:28]([F:29])=[C:27]([F:30])[C:26]([F:31])=[C:25]([F:32])[C:24]=2[F:33])([C:21]2[C:20]([F:56])=[C:19]([F:57])[C:18]([F:58])=[C:17]([F:59])[C:16]=2[F:15])[C:34]2[C:35]([F:44])=[C:36]([F:43])[C:37]([F:42])=[C:38]([F:41])[C:39]=2[F:40])=[C:46]([F:55])[C:47]([F:54])=[C:48]([F:53])[C:49]=1[F:52].[C:9]1([I+:8][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

参加物

4

反応物 2

HCID 73870Diphenyliodonium chlorideHCID 23709652Lithium tetrakis(pentafluorophenyl)borate

生成物 1

HCID 21918056Diphenyliodonium tetrakis(pentafluorophenyl)borate収率 75%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

7.17 g (or 22.6 mmol) of diphenyliodonium chloride were dissolved in 300 ml of water in a 1,000 ml Erlenmeyer flask. 15.52 g (or 22.6 mmol) of lithium tetrakis(pentafluorophenyl)borate in solution in 250 ml of water were added dropwise. The mixture was maintained under stirring for 30 minutes and was then filtered. The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light. 16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered.

後処理

  1. temperatureThe mixture was maintained
  2. filtrationwas then filtered
  3. customThe filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light
  4. custom16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered

出典と根拠

ORDレコード
ord-6384164cd22146bd8e8ee6bce72735ff
出典データセット
uspto-grants-1995_11
特許番号
US05468902

関連ノート

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