関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Alpha-Methylstyrene | HCID 7407 | — |
| 反応物 | Benzenecarbodithioic acid | HCID 67141 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | Cumyl dithiobenzoate | HCID 11065602 | 32.6% |
反応手順
A mixture of dithiobenzoic acid (10.59 g), a-methylstyrene (10 g) and carbon tetrachloride (40 mL) was heated at 70° C. for 4 hours. The resultant mixture was reduced to a crude oil which was purified by column chromatography (aluminium oxide (activity III), n-hexane eluent) to give 2-phenylprop-2-yl dithiobenzoate (5) (6.1 g, 32.6% yield) as a dark purple oil. 1H-nmr (CDCl3) d(ppm): 2.03 (s, 6H); 7.20-7.60 (m, 8H) and 7.86 (m, 2H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07250479B2 |
|---|
| 出典データセット | uspto-grants-2007_07 |
|---|
| ORD ID | ord-3cd00bcf174e4831bfb6f9b86e8987ab |
|---|
| 出典メモ | uspto-grants-2007_07 |
|---|
