3-Phenoxy-1,2-propanediol → Phenoxyacetaldehyde
反応式
I([O-])(=O)(=O)=O.[Na+].[O:7]([CH2:14][CH:15]([OH:18])CO)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>ClCCl>[O:7]([CH2:14][CH:15]=[O:18])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1参加物
4
実験手順
Sodium periodate (0.65 M in water, 20 mL) was added to a vigorously stirred suspension of silica gel (20 g) in dichloromethane (160 mL), followed by a solution of 3-phenoxy-1,2-propanediol (1.68 g, 10.0 mmol) in dichloromethane (20 mL). After stirring for 10 min the mixture was filtered and the filtrate was concentrated to give the subtitle compound (1.36 g, 100%).
後処理
- filtrationwas filtered
- concentrationthe filtrate was concentrated
出典と根拠
- ORDレコード
- ord-1e1e15121926420891672153556960f2
- 出典データセット
- uspto-grants-2010_06
- 特許番号
- US07728030B2
反応ノート
読み込み中…