Acrylate → Urethane acrylate

HRID 132020

反応式

HRID 132020 の反応式
[N-:1]=[C:2]=[O:3].[C:4]([O-:17])(=[O:16])[CH2:5][CH2:6]CCCCCCCCC.C([Sn+2]CCCC)CCC.[C:27]([O-])(=[O:39])[CH2:28]CCCCCCCCCC.C([O-])(=O)C=C>>[C:4]([OH:17])(=[O:16])[CH:5]=[CH2:6].[NH2:1][C:2]([O:39][CH2:27][CH3:28])=[O:3]

参加物

4

反応物 3

HCID 25188AcrylateHCID 105034Isocyanate2 回HCID 9809426Di-n-butyldilauryltin

生成物 1

HCID 21863578Urethane acrylate

反応条件

温度
70 °C

実験手順

A quantity of 0.1 moles of isocyanate terminated prepolymer and 0.1 ml of dibutyltin laurate were charged to a 500 ml glass kettle. The mixture was heated at 70° C. and air was purged through the reaction mixture and a solution of diol (0.05 moles) was added dropwise while the mixture was stirred at 200 RPM. After a two hour reaction, hydroyethyl acrylate (0.1 moles) was added to cap the residual isocyanate and the temperature of the kettle was increased to 77° C. After another two hours, a sample was withdrawn for analysis. The remainder was transferred to a bottle and stored in darkness.

後処理

  1. customair was purged through the reaction mixture
  2. additionwas added
  3. temperaturethe temperature of the kettle was increased to 77° C
  4. customa sample was withdrawn for analysis

出典と根拠

ORDレコード
ord-6636e235564b47d3810d88d2653baf63
出典データセット
uspto-grants-2008_06
特許番号
US07385078B2

関連ノート

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