化工社化工社 化学情報印刷レポート · 研究参考用
Formic Acid → 1,2-Dodecanediol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Formic Acid | HCID 284 | — |
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | 1-Dodecene | HCID 8183 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 1,2-Dodecanediol | HCID 92866 | — |
反応手順
336 g (2.00 mol) of 1-dodecene were reacted with 236 g of formic acid and 185 g of a 50% strength aqueous H2O2 solution in accordance with Example 4. 412 g of ethanol were employed for the Marlon AS3 acid-catalyzed transesterification, and the main fraction obtained after the workup by distillation was 99.5% pure, virtually odorless 1,2-dodecanediol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07385092B2 |
| 出典データセット | uspto-grants-2008_06 |
| ORD ID | ord-e3f2b7809e3f48e28f4d2541ab2247dc |
| 出典メモ | uspto-grants-2008_06 |