Hydrochloric Acid → 9,10-Dimethylanthracene-2-carboxylic acid

HRID 132796

反応式

HRID 132796 の反応式
[CH3:1][C:2]1[C:3]2[C:8]([C:9]([CH3:19])=[C:10]3[C:15]=1[CH:14]=[C:13](C(=O)C)[CH:12]=[CH:11]3)=[CH:7][CH:6]=[CH:5][CH:4]=2.Cl([O-])(=O)(=O)=[O:21].[Na+].Cl.[O:27]1[CH2:32]COCC1>>[CH3:1][C:2]1[C:3]2[C:8]([C:9]([CH3:19])=[C:10]3[C:15]=1[CH:14]=[C:13]([C:32]([OH:27])=[O:21])[CH:12]=[CH:11]3)=[CH:7][CH:6]=[CH:5][CH:4]=2

参加物

5

反応物 4

HCID 313Hydrochloric AcidHCID 312751,4-DioxaneHCID 522606Sodium PerchlorateHCID 124387722-Acetyl-9,10-dimethylanthracene

生成物 1

HCID 231095239,10-Dimethylanthracene-2-carboxylic acid

反応条件

温度
85 °C

実験手順

9,10-Dimethyl-2-acetylanthracene (1.2 g) was dissolved in dioxane (24 mL). An aqueous solution of sodium perchlorate (10 mL; effective chlorine concentration: 10 wt %) was then added, followed by reaction under stirring at 85° C. for 8 hours. The reaction mixture was chilled, and then rendered acidic with dilute hydrochloric acid. The resulting precipitate was collected by filtration, washed with a small amount of water, and then dried in vacuo to afford the target compound (1.16 g).

後処理

  1. customfollowed by reaction
  2. temperatureThe reaction mixture was chilled
  3. filtrationThe resulting precipitate was collected by filtration
  4. washwashed with a small amount of water
  5. customdried in vacuo

出典と根拠

ORDレコード
ord-06963fd2f68445c0a7be0ad03d8800fb
出典データセット
uspto-grants-2008_06
特許番号
US07388110B2

関連ノート

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