Toluene → 3-chloro-4,5-dihydro-5-methyl-6H-imidazo[1,5-a][1,4]benzodiazepine-6-thione

反応式

[CH3:18][O:19][c:20]1[cH:21][cH:22][c:23]([P:24]2(=[S:25])[S:26][P:28](=[S:29])([c:30]3[cH:31][cH:32][c:33]([O:34][CH3:35])[cH:36][cH:37]3)[S:27]2)[cH:38][cH:39]1.[CH3:40][c:41]1[cH:42][cH:43][cH:44][cH:45][cH:46]1.[Cl:1][c:2]1[n:3][cH:4][n:5]2[c:6]1[CH2:7][N:8]([CH3:17])[C:9](=[O:16])[c:10]1[c:11]-2[cH:12][cH:13][cH:14][cH:15]1>>[Cl:1][c:2]1[n:3][cH:4][n:5]2[c:6]1[CH2:7][N:8]([CH3:17])[C:9](=[S:27])[c:10]1[c:11]-2[cH:12][cH:13][cH:14][cH:15]1

参加物

反応物 3

HCID 1140Toluene

HCID 87949Lawesson's reagent

HCID 205232833-chloro-4,5-dihydro-5-methyl-6H-imidazo[1,5-a][1,4]benzodiazepin-6-one

生成物 1

HCID 205232813-chloro-4,5-dihydro-5-methyl-6H-imidazo[1,5-a][1,4]benzodiazepine-6-thione

出典と根拠

ORDレコード: ord-88cbf6e111804d7f87d8066db8d15b88
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…