Bis(trimethylstannyl)indene → HCID 178477784、化合物

HRID 1354511ノート

反応式

HRID 1354511 の反応式
[Cl-:1].[Cl-].[Cl-].[CH:4]1([Zr+3:9])[CH:8]=[CH:7][CH:6]=[CH:5]1.[CH3:10][Sn:11]([C:14]1[CH:15]([Sn](C)(C)C)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:1].[CH3:10][Sn:11]([C:14]1[CH:15]([Zr+2:9][CH:4]2[CH:8]=[CH:7][CH:6]=[CH:5]2)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]

参加物

4

反応物 2

HCID 69432104Bis(trimethylstannyl)indeneHCID 178478629HCID 178478629、化合物

生成物 1

HCID 178477784HCID 178477784、化合物収率 177.1%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒2 回

実験手順

Cyclopentadienylzirconium trichloride (CpZrCl3, 3.94 g, 15.0 mmol) which was slurrified by adding toluene of 70 ml was added into the mixed solution including bis(trimethylstannyl)indene (6.75 g, 15.28 mmol) and toluene of 100 ml, and then reacted for 21 hours at 85° C. Yellowish (trimethylstannyl-indenyl)(cyclopentadienyl)zirconium dichloride compound (6.71 g, yield: 86%) was obtained by a series of processes, such as removing toluene from reactant, slurrifying the obtained solid by adding hexane (100 ml) and filtering the slurry.

後処理

  1. additionwas added into the mixed solution
  2. customreacted for 21 hours at 85° C

出典と根拠

ORDレコード
ord-3a68c936c1b949759705c002a0c1a4d3
出典データセット
uspto-grants-2007_05
特許番号
US07223824B2

反応ノート

読み込み中…